OYO BUTURI
Vol.88
No.4
2019
4
20194884267
OYO BUTURI Vol.88 No.4 (2019)
Our Research

Conduction mechanism of proton in oxides

Yoshihiro YAMAZAKI1, Akihide KUWABARA2

The transport mechanism in proton-conducting oxides, specifically Sc- and Y-doped barium zirconates, is discussed based on the results of electrochemical experiments and ab initio calculations. Proton trapping was observed for each case. The second nearest proton site was the trapping site for Y-doping, which was understood by the difference in the local hydrogen bonding state.

  • 1 Kyushu University
  • 2 Japan Fine Ceramics Center
OYO BUTURI Vol.88 No.4 p.267 (2019)